Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes

Intramolecular nucleophilic addition of carbanions generated from: N -benzylamides to cyclopropenes

An unusual reaction is described, involving a formal intramolecular nucleophilic substitution of bromocyclopropanes with nitrogen ylides generated in situ from N-benzyl carboxamides. It is shown that this reaction involves cyclopropene intermediates and allows for the facile and expeditious preparat...

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Главные авторы:	Aksenov, N. A., Аксенов, Н. А., Rubin, M. A., Рубин, М. А.
Формат:	Статья
Язык:	English
Опубликовано:	Royal Society of Chemistry 2018
Темы:	Addition reaction Scaffolds Carboxamides Cyclopropene Nucleophilic addition Nucleophilic substitutions Reaction intermediate
Online-ссылка:	https://dspace.ncfu.ru:443/handle/20.500.12258/395
Метки:	Добавить метку Нет меток, Требуется 1-ая метка записи!

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