Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement
Condensation of 2-naphthol, furfural, and acetamide in the presence of boric acid as acidic catalyst has led to Betti product N-[furan-2-yl(2-hydroxynaphthalen-1-yl)methyl]acetamide along with a new 10,10-dihydrocyclopenta[b]naphtho[1,2-d]furan derivative, which resulted from rare carbo-Piancatelli...
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| स्वरूप: | Статья |
| भाषा: | English |
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Springer New York LLC
2019
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| ऑनलाइन पहुंच: | https://www.scopus.com/record/display.uri?eid=2-s2.0-85065445650&origin=resultslist&sort=plf-f&src=s&st1=%09Betti+reaction+of+2-naphthol%2c+furfural%2c+and+acetamide%3a+an+unexpected+case+of+secondary+carbo-Piancatelli+rearrangement&st2=&sid=454506f010f43a553139b663dbb5ea50&sot=b&sdt=b&sl=134&s=TITLE-ABS-KEY%28%09Betti+reaction+of+2-naphthol%2c+furfural%2c+and+acetamide%3a+an+unexpected+case+of+secondary+carbo-Piancatelli+rearrangement%29&relpos=0&citeCnt=0&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/5437 |
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ir-20.500.12258-54372020-02-17T12:58:17Z Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement Demidov, O. P. Демидов, О. П. 2-naphthol Betti reaction Boric acid Carbo-Piancatelli rearrangement Furfural Multicomponent reaction Condensation of 2-naphthol, furfural, and acetamide in the presence of boric acid as acidic catalyst has led to Betti product N-[furan-2-yl(2-hydroxynaphthalen-1-yl)methyl]acetamide along with a new 10,10-dihydrocyclopenta[b]naphtho[1,2-d]furan derivative, which resulted from rare carbo-Piancatelli rearrangement. The structure is confirmed by 1 H, 13 C NMR, HRMS, and X-ray analyses. Mechanism of the transformation is discussed 2019-05-20T13:34:47Z 2019-05-20T13:34:47Z 2019 Статья Gutnov, A.V., Abaev, V.T., Demidov, O.P. Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement // Chemistry of Heterocyclic Compounds. - 2019. - Volume 55. - Issue 3. - Pages 280-282 https://www.scopus.com/record/display.uri?eid=2-s2.0-85065445650&origin=resultslist&sort=plf-f&src=s&st1=%09Betti+reaction+of+2-naphthol%2c+furfural%2c+and+acetamide%3a+an+unexpected+case+of+secondary+carbo-Piancatelli+rearrangement&st2=&sid=454506f010f43a553139b663dbb5ea50&sot=b&sdt=b&sl=134&s=TITLE-ABS-KEY%28%09Betti+reaction+of+2-naphthol%2c+furfural%2c+and+acetamide%3a+an+unexpected+case+of+secondary+carbo-Piancatelli+rearrangement%29&relpos=0&citeCnt=0&searchTerm= http://hdl.handle.net/20.500.12258/5437 en Chemistry of Heterocyclic Compounds application/pdf application/pdf Springer New York LLC |
| institution |
СКФУ |
| collection |
Репозиторий |
| language |
English |
| topic |
2-naphthol Betti reaction Boric acid Carbo-Piancatelli rearrangement Furfural Multicomponent reaction |
| spellingShingle |
2-naphthol Betti reaction Boric acid Carbo-Piancatelli rearrangement Furfural Multicomponent reaction Demidov, O. P. Демидов, О. П. Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement |
| description |
Condensation of 2-naphthol, furfural, and acetamide in the presence of boric acid as acidic catalyst has led to Betti product N-[furan-2-yl(2-hydroxynaphthalen-1-yl)methyl]acetamide along with a new 10,10-dihydrocyclopenta[b]naphtho[1,2-d]furan derivative, which resulted from rare carbo-Piancatelli rearrangement. The structure is confirmed by 1 H, 13 C NMR, HRMS, and X-ray analyses. Mechanism of the transformation is discussed |
| format |
Статья |
| author |
Demidov, O. P. Демидов, О. П. |
| author_facet |
Demidov, O. P. Демидов, О. П. |
| author_sort |
Demidov, O. P. |
| title |
Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement |
| title_short |
Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement |
| title_full |
Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement |
| title_fullStr |
Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement |
| title_full_unstemmed |
Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement |
| title_sort |
betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-piancatelli rearrangement |
| publisher |
Springer New York LLC |
| publishDate |
2019 |
| url |
https://www.scopus.com/record/display.uri?eid=2-s2.0-85065445650&origin=resultslist&sort=plf-f&src=s&st1=%09Betti+reaction+of+2-naphthol%2c+furfural%2c+and+acetamide%3a+an+unexpected+case+of+secondary+carbo-Piancatelli+rearrangement&st2=&sid=454506f010f43a553139b663dbb5ea50&sot=b&sdt=b&sl=134&s=TITLE-ABS-KEY%28%09Betti+reaction+of+2-naphthol%2c+furfural%2c+and+acetamide%3a+an+unexpected+case+of+secondary+carbo-Piancatelli+rearrangement%29&relpos=0&citeCnt=0&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/5437 |
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