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Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement

Condensation of 2-naphthol, furfural, and acetamide in the presence of boric acid as acidic catalyst has led to Betti product N-[furan-2-yl(2-hydroxynaphthalen-1-yl)methyl]acetamide along with a new 10,10-dihydrocyclopenta[b]naphtho[1,2-d]furan derivative, which resulted from rare carbo-Piancatelli...

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Главные авторы: Demidov, O. P., Демидов, О. П.
Формат: Статья
Язык:English
Опубликовано: Springer New York LLC 2019
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Online-ссылка:https://dspace.ncfu.ru/handle/20.500.12258/5437
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spelling ir-20.500.12258-54372025-02-13T12:56:52Z Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement Demidov, O. P. Демидов, О. П. 2-naphthol Betti reaction Boric acid Carbo-Piancatelli rearrangement Furfural Multicomponent reaction Condensation of 2-naphthol, furfural, and acetamide in the presence of boric acid as acidic catalyst has led to Betti product N-[furan-2-yl(2-hydroxynaphthalen-1-yl)methyl]acetamide along with a new 10,10-dihydrocyclopenta[b]naphtho[1,2-d]furan derivative, which resulted from rare carbo-Piancatelli rearrangement. The structure is confirmed by 1 H, 13 C NMR, HRMS, and X-ray analyses. Mechanism of the transformation is discussed 2019-05-20T13:34:47Z 2019-05-20T13:34:47Z 2019 Статья Gutnov, A.V., Abaev, V.T., Demidov, O.P. Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement // Chemistry of Heterocyclic Compounds. - 2019. - Volume 55. - Issue 3. - Pages 280-282 http://hdl.handle.net/20.500.12258/5437 en Chemistry of Heterocyclic Compounds application/pdf application/pdf Springer New York LLC
institution СКФУ
collection Репозиторий
language English
topic 2-naphthol
Betti reaction
Boric acid
Carbo-Piancatelli rearrangement
Furfural
Multicomponent reaction
spellingShingle 2-naphthol
Betti reaction
Boric acid
Carbo-Piancatelli rearrangement
Furfural
Multicomponent reaction
Demidov, O. P.
Демидов, О. П.
Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement
description Condensation of 2-naphthol, furfural, and acetamide in the presence of boric acid as acidic catalyst has led to Betti product N-[furan-2-yl(2-hydroxynaphthalen-1-yl)methyl]acetamide along with a new 10,10-dihydrocyclopenta[b]naphtho[1,2-d]furan derivative, which resulted from rare carbo-Piancatelli rearrangement. The structure is confirmed by 1 H, 13 C NMR, HRMS, and X-ray analyses. Mechanism of the transformation is discussed
format Статья
author Demidov, O. P.
Демидов, О. П.
author_facet Demidov, O. P.
Демидов, О. П.
author_sort Demidov, O. P.
title Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement
title_short Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement
title_full Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement
title_fullStr Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement
title_full_unstemmed Betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-Piancatelli rearrangement
title_sort betti reaction of 2-naphthol, furfural, and acetamide: an unexpected case of secondary carbo-piancatelli rearrangement
publisher Springer New York LLC
publishDate 2019
url https://dspace.ncfu.ru/handle/20.500.12258/5437
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