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Synthesis of meta-substituted anilines via a three-component reaction of acetone, amines, and 1,3-diketones

Synthesis of meta-substituted anilines via a three-component reaction of acetone, amines, and 1,3-diketones

A facile method for the synthesis of meta-substituted arylamines from acyclic precursors was developed. This method is based on three-component cyclo-condensation/aromatization of in situ generated imines of acetone with 1,3-diketones either under conventional heating or under microwave irradiation....

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Detaylı Bibliyografya
Asıl Yazarlar: Rubin, M. A., Рубин, М. А.
Materyal Türü: Статья
Dil:English
Baskı/Yayın Bilgisi: ROYAL SOC CHEMISTRY 2019
Konular:
Pd-at-pani
Pharmacokinetic properties
Trifluoromethyl ketones
Pactical catalyst
Discovery
Inhibitors
Potent
Benzannulation
Condensation
Bicalutamide
Online Erişim:http://apps.webofknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=1&SID=C2RI3BOJAwOaexjHfEf&page=1&doc=1
https://dspace.ncfu.ru/handle/20.500.12258/9753
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Diğer Bilgiler
Özet:A facile method for the synthesis of meta-substituted arylamines from acyclic precursors was developed. This method is based on three-component cyclo-condensation/aromatization of in situ generated imines of acetone with 1,3-diketones either under conventional heating or under microwave irradiation. The utility of this methodology is illustrated by the possibility of a gram scale synthesis of various anilines from readily available reagents

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