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Directed nucleophilic addition of phenoxides to cyclopropenes

Directed nucleophilic addition of phenoxides to cyclopropenes

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The alkali metal-templated addition of aryloxides across the double bond of non-conjugated cyclopropenes is described. High cis-selectivity is achieved through a directing effect of a strategically positioned carboxamide functionality

Tallennettuna:
Bibliografiset tiedot
Päätekijät: Aksenov, N. A., Аксенов, Н. А., Rubin, M. A., Рубин, М. А.
Aineistotyyppi: Статья
Kieli:English
Julkaistu: Royal Society of Chemistry 2018
Aiheet:
Alkali metals
Carboxamides
Cyclopropenes
Double bonds
Nucleophilic additions
Templated
Addition reactions
Linkit:https://www.scopus.com/record/display.uri?eid=2-s2.0-85030682886&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=North+Caucasus+Federal+University&sid=a75f219f53d4022b97f1d2161feb9566&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Directed+nucleophilic+addition+of+phenoxides+to+cyclopropenes%29&relpos=2&citeCnt=2&searchTerm=
https://dspace.ncfu.ru/handle/20.500.12258/2765
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https://www.scopus.com/record/display.uri?eid=2-s2.0-85030682886&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=North+Caucasus+Federal+University&sid=a75f219f53d4022b97f1d2161feb9566&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Directed+nucleophilic+addition+of+phenoxides+to+cyclopropenes%29&relpos=2&citeCnt=2&searchTerm=
https://dspace.ncfu.ru/handle/20.500.12258/2765

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