Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones
The reaction of tetraalkynyltin with aldehydes was studied for the first time. The reaction was shown to proceed as a tandem process of nucleophilic addition of tin acetylide to aldehyde followed by Oppenauer-type oxidation of produced tin alcoholates, and may be used as a convenient one-pot approac...
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Royal Society of Chemistry
2018
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oai:10.200.131.19:20.500.12258-29742018-09-14T08:44:25Z Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Aldehyde derivative Ketone derivative Stannic chloride Oxidative coupling The reaction of tetraalkynyltin with aldehydes was studied for the first time. The reaction was shown to proceed as a tandem process of nucleophilic addition of tin acetylide to aldehyde followed by Oppenauer-type oxidation of produced tin alcoholates, and may be used as a convenient one-pot approach to acetylenic ketones. The advantages and limitations of the proposed method are discussed 2018-09-14T08:43:35Z 2018-09-14T08:43:35Z 2017 Статья Levashov, A.S., Aksenov, N.A., Aksenova, I.V., Konshin, V.V. Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones // New Journal of Chemistry. - 2017. - Volume 41. - Issue 16. - Pages 8297-8304 https://www.scopus.com/record/display.uri?eid=2-s2.0-85027030617&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=1af4e03e943ebe5b20c0bfa6c2ca02b9&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Oxidative+coupling+of+tetraalkynyltin+with+aldehydes+leading+to+alkynyl+ketones%29&relpos=1&citeCnt=3&searchTerm= http://hdl.handle.net/20.500.12258/2974 en New Journal of Chemistry application/pdf application/pdf Royal Society of Chemistry |
| institution |
СКФУ |
| collection |
Репозиторий |
| language |
English |
| topic |
Aldehyde derivative Ketone derivative Stannic chloride Oxidative coupling |
| spellingShingle |
Aldehyde derivative Ketone derivative Stannic chloride Oxidative coupling Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones |
| description |
The reaction of tetraalkynyltin with aldehydes was studied for the first time. The reaction was shown to proceed as a tandem process of nucleophilic addition of tin acetylide to aldehyde followed by Oppenauer-type oxidation of produced tin alcoholates, and may be used as a convenient one-pot approach to acetylenic ketones. The advantages and limitations of the proposed method are discussed |
| format |
Статья |
| author |
Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. |
| author_facet |
Aksenov, N. A. Аксенов, Н. А. Aksenova, I. V. Аксенова, И. В. |
| author_sort |
Aksenov, N. A. |
| title |
Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones |
| title_short |
Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones |
| title_full |
Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones |
| title_fullStr |
Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones |
| title_full_unstemmed |
Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones |
| title_sort |
oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones |
| publisher |
Royal Society of Chemistry |
| publishDate |
2018 |
| url |
https://www.scopus.com/record/display.uri?eid=2-s2.0-85027030617&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=1af4e03e943ebe5b20c0bfa6c2ca02b9&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Oxidative+coupling+of+tetraalkynyltin+with+aldehydes+leading+to+alkynyl+ketones%29&relpos=1&citeCnt=3&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/2974 |
| work_keys_str_mv |
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