Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones
The reaction of tetraalkynyltin with aldehydes was studied for the first time. The reaction was shown to proceed as a tandem process of nucleophilic addition of tin acetylide to aldehyde followed by Oppenauer-type oxidation of produced tin alcoholates, and may be used as a convenient one-pot approac...
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| Hoofdauteurs: | , , , |
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| Formaat: | Статья |
| Taal: | English |
| Gepubliceerd in: |
Royal Society of Chemistry
2018
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| Onderwerpen: | |
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