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Low-Temperature Synthesis of Tungsten Silicates with Pyrochlore and Tungsten Bronze Structure

Polyoxotungstosilicates with the general formulas Cat4[SiW12O40] • mH2O and Cat6[SiW11O39Ni(H2O)] • nH2O were synthesized, where Cat = Rb+, Cs+, (CH3)4N+. By means of IR spectroscopy and x-ray diffraction analysis, it was shown that the compounds have the Keggin anion structure. The thermolysis of t...

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Autors principals: Chebyshev, K. A., Чебышев, К. А.
Format: Статья
Idioma:English
Publicat: Springer 2024
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Accés en línia:https://dspace.ncfu.ru/handle/123456789/29333
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