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Structure Study of the Reaction Product of Formyl-Substituted Spiropyran of 1,3-Benzoxazin-4-One Series with Malonodinitrile

Synthesis is reported of new spiropyran based on 1,3-benzoxazin-4-one heterocycle with the vinyl-dicarbonitrile fragment at the 8′ position of the 2H-chromene part of the molecule. The structure of the isolated product is confirmed by NMR and mass spectrometry along with single crystal X-ray diffrac...

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Autors principals: Pobedinskaya, D. Y., Побединская, Д. Ю.
Format: Статья
Idioma:English
Publicat: Pleiades Publishing 2025
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Accés en línia:https://dspace.ncfu.ru/handle/123456789/30525
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spelling ir-123456789-305252025-06-19T08:14:23Z Structure Study of the Reaction Product of Formyl-Substituted Spiropyran of 1,3-Benzoxazin-4-One Series with Malonodinitrile Pobedinskaya, D. Y. Побединская, Д. Ю. 1,3-benzoxazine Condensation Knoevenagel reaction Malononitrile Single crystal X-ray diffraction analysis Spiropyran Synthesis is reported of new spiropyran based on 1,3-benzoxazin-4-one heterocycle with the vinyl-dicarbonitrile fragment at the 8′ position of the 2H-chromene part of the molecule. The structure of the isolated product is confirmed by NMR and mass spectrometry along with single crystal X-ray diffraction. Intermolecular interactions are stuided in the crystal using Mercury and CrystalExplorer program packages. 2025-06-19T08:03:01Z 2025-06-19T08:03:01Z 2025 Статья Dmitriev V.S., Pugachev A.D., Tkachev V.V., Utenyshev A.N., Pobedinskaya D.Y., Stankevich N.V., Chepurnoi P.B., Aldoshin S.M., Metelitsa A.V., Ozhogin I.V. Structure Study of the Reaction Product of Formyl-Substituted Spiropyran of 1,3-Benzoxazin-4-One Series with Malonodinitrile // Journal of Structural Chemistry. - 2025. - 66 (5). - art. no. 8. - pp. 930 - 938. - DOI: 10.1134/S0022476625050063 https://dspace.ncfu.ru/handle/123456789/30525 en Journal of Structural Chemistry application/pdf application/pdf Pleiades Publishing
institution СКФУ
collection Репозиторий
language English
topic 1,3-benzoxazine
Condensation
Knoevenagel reaction
Malononitrile
Single crystal X-ray diffraction analysis
Spiropyran
spellingShingle 1,3-benzoxazine
Condensation
Knoevenagel reaction
Malononitrile
Single crystal X-ray diffraction analysis
Spiropyran
Pobedinskaya, D. Y.
Побединская, Д. Ю.
Structure Study of the Reaction Product of Formyl-Substituted Spiropyran of 1,3-Benzoxazin-4-One Series with Malonodinitrile
description Synthesis is reported of new spiropyran based on 1,3-benzoxazin-4-one heterocycle with the vinyl-dicarbonitrile fragment at the 8′ position of the 2H-chromene part of the molecule. The structure of the isolated product is confirmed by NMR and mass spectrometry along with single crystal X-ray diffraction. Intermolecular interactions are stuided in the crystal using Mercury and CrystalExplorer program packages.
format Статья
author Pobedinskaya, D. Y.
Побединская, Д. Ю.
author_facet Pobedinskaya, D. Y.
Побединская, Д. Ю.
author_sort Pobedinskaya, D. Y.
title Structure Study of the Reaction Product of Formyl-Substituted Spiropyran of 1,3-Benzoxazin-4-One Series with Malonodinitrile
title_short Structure Study of the Reaction Product of Formyl-Substituted Spiropyran of 1,3-Benzoxazin-4-One Series with Malonodinitrile
title_full Structure Study of the Reaction Product of Formyl-Substituted Spiropyran of 1,3-Benzoxazin-4-One Series with Malonodinitrile
title_fullStr Structure Study of the Reaction Product of Formyl-Substituted Spiropyran of 1,3-Benzoxazin-4-One Series with Malonodinitrile
title_full_unstemmed Structure Study of the Reaction Product of Formyl-Substituted Spiropyran of 1,3-Benzoxazin-4-One Series with Malonodinitrile
title_sort structure study of the reaction product of formyl-substituted spiropyran of 1,3-benzoxazin-4-one series with malonodinitrile
publisher Pleiades Publishing
publishDate 2025
url https://dspace.ncfu.ru/handle/123456789/30525
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