Michael addition of amines to sterically crowded ortho-benzoquinone completed with unprecedented 1,2-shift of a tert-butyl group

Michael addition of amines to sterically crowded ortho-benzoquinone completed with unprecedented 1,2-shift of a tert-butyl group

A strong electron-withdrawing nitro group introduced into the 6-position of 3,5-di-(tert-butyl)-1,2-benzoquinone provides for activation of the sterically blocked Michael addition reaction channel. Addition of amines to the quinone is followed by a concerted 1,2-migration of a tert-butyl group to af...

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書目詳細資料
Главные авторы:	Demidov, O. P., Демидов, О. П.
格式:	Статья
語言:	English
出版:	Elsevier Ltd 2021
主題:	6-Nitrocyclohexa-2,5-dienones Density functional calculations alkyl 1,2-migration Michael addition Quinones
在線閱讀:	https://dspace.ncfu.ru/handle/20.500.12258/14784
標簽:	添加標簽沒有標簽, 成為第一個標記此記錄!

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