Does electrophilic activation of nitroalkanes in polyphosphoric acid involve formation of nitrile oxides?

The mechanistic rationale involving activation of nitroalkanes towards interaction with nucleophilic reagents in the presence of polyphosphoric acid (PPA) was re-evaluated. Could nitrile oxide moieties be formed during this process? This experiment demonstrates that at least in some cases this could...

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Главные авторы:	Aksenov, A. V., Аксенов, А. В., Aksenov, N. A., Аксенов, Н. А., Kirilov, N. K., Кирилов, Н. К., Skomorokhov, A. A., Скоморохов, А. А., Aksenov, D. A., Аксенов, Д. А., Kurenkov, I. A., Куренков, И. А., Rubin, M. A., Рубин, М. А.
Format:	Статья
Sprog:	English
Udgivet:	ROYAL SOC CHEMISTRY 2021
Fag:	Nucleophilic-addition Michael addition Benzoxazoles Reactivity Catalyst
Online adgang:	https://dspace.ncfu.ru/handle/20.500.12258/18317
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https://dspace.ncfu.ru/handle/20.500.12258/18317

Does electrophilic activation of nitroalkanes in polyphosphoric acid involve formation of nitrile oxides?

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