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Does electrophilic activation of nitroalkanes in polyphosphoric acid involve formation of nitrile oxides?

Does electrophilic activation of nitroalkanes in polyphosphoric acid involve formation of nitrile oxides?

The mechanistic rationale involving activation of nitroalkanes towards interaction with nucleophilic reagents in the presence of polyphosphoric acid (PPA) was re-evaluated. Could nitrile oxide moieties be formed during this process? This experiment demonstrates that at least in some cases this could...

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Hoofdauteurs: Aksenov, A. V., Аксенов, А. В., Aksenov, N. A., Аксенов, Н. А., Kirilov, N. K., Кирилов, Н. К., Skomorokhov, A. A., Скоморохов, А. А., Aksenov, D. A., Аксенов, Д. А., Kurenkov, I. A., Куренков, И. А., Rubin, M. A., Рубин, М. А.
Formaat: Статья
Taal:English
Gepubliceerd in: ROYAL SOC CHEMISTRY 2021
Onderwerpen:
Nucleophilic-addition
Michael addition
Benzoxazoles
Reactivity
Catalyst
Online toegang:https://dspace.ncfu.ru/handle/20.500.12258/18317
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https://dspace.ncfu.ru/handle/20.500.12258/18317

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