Does electrophilic activation of nitroalkanes in polyphosphoric acid involve formation of nitrile oxides?
The mechanistic rationale involving activation of nitroalkanes towards interaction with nucleophilic reagents in the presence of polyphosphoric acid (PPA) was re-evaluated. Could nitrile oxide moieties be formed during this process? This experiment demonstrates that at least in some cases this could...
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| Главные авторы: | , , , , , , , , , , , , , |
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| Формат: | Статья |
| Язык: | English |
| Опубликовано: |
ROYAL SOC CHEMISTRY
2021
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| Темы: | |
| Online-ссылка: | https://dspace.ncfu.ru/handle/20.500.12258/18317 |
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