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Does electrophilic activation of nitroalkanes in polyphosphoric acid involve formation of nitrile oxides?

Does electrophilic activation of nitroalkanes in polyphosphoric acid involve formation of nitrile oxides?

The mechanistic rationale involving activation of nitroalkanes towards interaction with nucleophilic reagents in the presence of polyphosphoric acid (PPA) was re-evaluated. Could nitrile oxide moieties be formed during this process? This experiment demonstrates that at least in some cases this could...

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Detaylı Bibliyografya
Asıl Yazarlar: Aksenov, A. V., Аксенов, А. В., Aksenov, N. A., Аксенов, Н. А., Kirilov, N. K., Кирилов, Н. К., Skomorokhov, A. A., Скоморохов, А. А., Aksenov, D. A., Аксенов, Д. А., Kurenkov, I. A., Куренков, И. А., Rubin, M. A., Рубин, М. А.
Materyal Türü: Статья
Dil:English
Baskı/Yayın Bilgisi: ROYAL SOC CHEMISTRY 2021
Konular:
Nucleophilic-addition
Michael addition
Benzoxazoles
Reactivity
Catalyst
Online Erişim:https://dspace.ncfu.ru/handle/20.500.12258/18317
Etiketler: Etiketle
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https://dspace.ncfu.ru/handle/20.500.12258/18317

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