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One-Pot Synthesis of (E)-2-(3-Oxoindolin-2-Ylidene)-2-Arylacetonitriles

One-Pot Synthesis of (E)-2-(3-Oxoindolin-2-Ylidene)-2-Arylacetonitriles

A highly efficient and expeditious one-pot approach towards 2-(3-oxoindolin-2-yl)acetonitriles was designed, which involves a base-assisted aldol reaction of ortho-nitroacetophenones, followed by hydrocyanation, triggering an unusual reductive cyclization reaction.

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Autors principals: Aksenov, N. A., Аксенов, Н. А., Aksenov, A. V., Аксенов, А. В., Kurenkov, I. A., Куренков, И. А., Kirilov, N. K., Кирилов, Н. К., Aksenov, D. A., Аксенов, Д. А., Arutiunov, N. A., Арутюнов, Н. А., Aksenova, D. S., Аксенова, Д. С., Rubin, M. A., Рубин, М. А.
Format: Статья
Idioma:English
Publicat: MDPI 2022
Matèries:
Brønsted acid catalysis
Cascade transformations
Indoles
Nitroalkanes
Rearrangements
Accés en línia:https://dspace.ncfu.ru/handle/20.500.12258/19606
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Internet

https://dspace.ncfu.ru/handle/20.500.12258/19606

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