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Directed RhI-catalyzed asymmetric hydroboration of prochiral 1-arylcycloprop-2-ene-1-carboxylic acid derivatives

Directed RhI-catalyzed asymmetric hydroboration of prochiral 1-arylcycloprop-2-ene-1-carboxylic acid derivatives

A full account on rhodium-catalyzed asymmetric, directed hydroboration of functionalized prochiral cyclopropenes affording enantiomerically enriched cyclopropylboronates is reported. The scope and limitations of two alternate directing groups, ester and carboxamide, are evaluated. It was found that...

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Главные авторы: Rubin, M. A., Рубин, М. А.
格式: Статья
語言:English
出版: Wiley-VCH Verlag 2018
主題:
Asymmetric catalysis
Cyclopropenes
Hydroboration
Protecting groupsr
Rhodium
在線閱讀:https://www.scopus.com/record/display.uri?eid=2-s2.0-85038430036&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=nort*+caucas*+fed*+univ*&sid=2cf89b62d1430faea2513c9ed4dc1d39&sot=afnl&sdt=afsp&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=14&citeCnt=1&searchTerm=
https://dspace.ncfu.ru:443/handle/20.500.12258/217
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https://www.scopus.com/record/display.uri?eid=2-s2.0-85038430036&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=nort*+caucas*+fed*+univ*&sid=2cf89b62d1430faea2513c9ed4dc1d39&sot=afnl&sdt=afsp&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=14&citeCnt=1&searchTerm=
https://dspace.ncfu.ru:443/handle/20.500.12258/217

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