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Nitrovinylindoles as Heterotrienes: Electrocyclic Cyclization En Route to β-Carbolines: Total Synthesis of Alkaloids Norharmane, Harmane, and Eudistomin N

Nitrovinylindoles as Heterotrienes: Electrocyclic Cyclization En Route to β-Carbolines: Total Synthesis of Alkaloids Norharmane, Harmane, and Eudistomin N

Unusual cascade transformation was developed involving microwave assisted electrocyclic cyclization of aci (alkylideneazinic acid) forms of nitrovinylindoles acting as heterotrienes. Subsequent one-pot reduction allowed for efficient access to β-carbolines, including several natural products, alkalo...

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Autors principals: Aksenov, N. A., Аксенов, Н. А., Arutiunov, N. A., Арутюнов, Н. А., Aksenov, A. V., Аксенов, А. В., Aksenova, I. V., Аксенова, И. В., Aleksandrova, E. V., Александрова, Е. В., Aksenov, D. A., Аксенов, Д. А., Rubin, M. A., Рубин, М. А.
Format: Статья
Idioma:English
Publicat: American Chemical Society 2022
Matèries:
Alkaloids
Biological products
Carbolines
Cyclization
Harmine
Accés en línia:https://dspace.ncfu.ru/handle/20.500.12258/21932
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https://dspace.ncfu.ru/handle/20.500.12258/21932

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