Organometallic Synthesis of 2,3,6,7-Tetrasubstituted 1,8-Bis(dimethylamino)naphthalenes for Investigation of the Double Buttressing Effect in Proton Sponges
The lithiation of 2,7-disubstituted derivatives of 1,8-bis(dimethylamino)naphthalene (DMAN, proton sponge) bearing potentially ortho-directing OMe, NMe2, and SMe groups was studied. It has been shown that OMe groups facilitate selective dual β-lithiation of the naphthalene moiety while the 2(7)-NMe2...
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| Главные авторы: | , |
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| Format: | Статья |
| Jezik: | English |
| Izdano: |
2023
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| Teme: | |
| Online dostop: | https://dspace.ncfu.ru/handle/20.500.12258/22272 |
| Oznake: |
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