Metal-templated assembly of cyclopropane-fused diazepanones and diazecanones via exo- trig nucleophilic cyclization of cyclopropenes with tethered carbamates
A strain-release-driven, cation-templated nucleophilic 7- and 8-exo-trig-cyclization of tethered Boc-protected amines to cyclopropenes is described. The featured reaction proceeds in diastereo- and regioselective fashion and allows for preparation of the corresponding 2,5-diazabicyclo[5.1.0]octan-6-...
Αποθηκεύτηκε σε:
| Κύριοι συγγραφείς: | , |
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| Μορφή: | Статья |
| Γλώσσα: | English |
| Έκδοση: |
American Chemical Society
2018
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| Θέματα: | |
| Διαθέσιμο Online: | https://www.scopus.com/record/display.uri?eid=2-s2.0-85056148282&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=6bb4e38e48c5091ac82975132bd42355&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Metal-Templated+Assembly+of+Cyclopropane-Fused+Diazepanones+and+Diazecanones+via+exo-+trig+Nucleophilic+Cyclization+of+Cyclopropenes+with+Tethered+Carbamates%29&relpos=0&citeCnt=0&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/3445 |
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https://www.scopus.com/record/display.uri?eid=2-s2.0-85056148282&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=6bb4e38e48c5091ac82975132bd42355&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Metal-Templated+Assembly+of+Cyclopropane-Fused+Diazepanones+and+Diazecanones+via+exo-+trig+Nucleophilic+Cyclization+of+Cyclopropenes+with+Tethered+Carbamates%29&relpos=0&citeCnt=0&searchTerm=https://dspace.ncfu.ru/handle/20.500.12258/3445