Metal-free ring expansion of indoles with nitroalkenes: A simple, modular approach to 3-substituted 2-quinolones
3-Substituted 2-quinolones are obtained via a novel metal-free transannulation reaction of 2-nitroolefins with 2-substituted indoles in polyphosphoric acid. This acid-mediated cascade transformation operates via the ANRORC (Addition of Nucleophile, Ring Opening, and Ring Closure) mechanism and can b...
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| Главные авторы: | , , , , , , , , , |
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| פורמט: | Статья |
| שפה: | English |
| יצא לאור: |
Royal Society of Chemistry
2019
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| גישה מקוונת: | https://www.scopus.com/record/display.uri?eid=2-s2.0-84921311817&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=3a73d74600efaa7e503fb84a84113fb0&sot=afnl&sdt=sisr&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Metal-free+ring+expansion+of+indoles+with+nitroalkenes%3a+A+simple%2c+modular+approach+to+3-substituted+2-quinolones%29&relpos=4&citeCnt=23&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/4247 |
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https://www.scopus.com/record/display.uri?eid=2-s2.0-84921311817&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=3a73d74600efaa7e503fb84a84113fb0&sot=afnl&sdt=sisr&cluster=scopubyr%2c%222015%22%2ct&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Metal-free+ring+expansion+of+indoles+with+nitroalkenes%3a+A+simple%2c+modular+approach+to+3-substituted+2-quinolones%29&relpos=4&citeCnt=23&searchTerm=https://dspace.ncfu.ru/handle/20.500.12258/4247