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Nucleophilic addition of amide anions to 1-methyl-5(6,7,8)-nitroquinolinium salts

Nucleophilic addition of amide anions to 1-methyl-5(6,7,8)-nitroquinolinium salts

The stable adducts, N-(1-methyl-5(6,7,8)-nitro-1,2-dihydroquinolin-2-yl)benzamides were synthesized for the first time by the action of amide anions of aromatic acids on the N-methyl salts of 5-, 6-, 7-, and 8-nitroquinolines in anhydrous MeCN. Oxidative dehydrogenation of these amides afforded aroy...

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Главные авторы: Avakyan, E. K., Авакян, Е. К., Amangasieva, G. A., Амангазиева, Г. А., Demidov, O. P., Демидов, О. П., Borovleva, A. A., Боровлева, А. А., Beketova, E. S., Бекетова, Е. С., Nechaeva, O. A., Нечаева, О. А., Borovlev, I. V., Боровлев, И. В.
格式: Статья
语言:English
出版: Springer New York LLC 2019
主题:
Nitroquinoline N-methyl cations
Nitroquinolines
Nucleophilic addition
在线阅读:https://www.scopus.com/record/display.uri?eid=2-s2.0-85071603162&origin=resultslist&sort=plf-f&src=s&st1=Nucleophilic+addition+of+amide+anions+to+1-methyl-5+6%2c7%2c8-nitroquinolinium+salts&st2=&sid=1c5a6fe41babdcf93eed0c3d463275ee&sot=b&sdt=b&sl=95&s=TITLE-ABS-KEY%28Nucleophilic+addition+of+amide+anions+to+1-methyl-5+6%2c7%2c8-nitroquinolinium+salts%29&relpos=0&citeCnt=0&searchTerm=
https://dspace.ncfu.ru/handle/20.500.12258/7499
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总结:The stable adducts, N-(1-methyl-5(6,7,8)-nitro-1,2-dihydroquinolin-2-yl)benzamides were synthesized for the first time by the action of amide anions of aromatic acids on the N-methyl salts of 5-, 6-, 7-, and 8-nitroquinolines in anhydrous MeCN. Oxidative dehydrogenation of these amides afforded aroylimino derivatives of the corresponding 1-methyl-5(6,7,8)-nitro-2-quinolones

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