Synthesis of meta-substituted anilines via a three-component reaction of acetone, amines, and 1,3-diketones
A facile method for the synthesis of meta-substituted arylamines from acyclic precursors was developed. This method is based on three-component cyclo-condensation/aromatization of in situ generated imines of acetone with 1,3-diketones either under conventional heating or under microwave irradiation....
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| Główni autorzy: | , |
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| Format: | Статья |
| Język: | English |
| Wydane: |
ROYAL SOC CHEMISTRY
2019
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| Hasła przedmiotowe: | |
| Dostęp online: | http://apps.webofknowledge.com/full_record.do?product=WOS&search_mode=GeneralSearch&qid=1&SID=C2RI3BOJAwOaexjHfEf&page=1&doc=1 https://dspace.ncfu.ru/handle/20.500.12258/9753 |
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| Streszczenie: | A facile method for the synthesis of meta-substituted arylamines from acyclic precursors was developed. This method is based on three-component cyclo-condensation/aromatization of in situ generated imines of acetone with 1,3-diketones either under conventional heating or under microwave irradiation. The utility of this methodology is illustrated by the possibility of a gram scale synthesis of various anilines from readily available reagents |
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