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Electrophilically activated nitroalkanes in the synthesis of 6,7-dihydro-1H-cyclopenta[g]perimidines

Electrophilically activated nitroalkanes in the synthesis of 6,7-dihydro-1H-cyclopenta[g]perimidines

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A highly efficient synthetic route to 6,7-dihydro-1H-cyclopenta[gh]perimidines has been proposed on the basis of a novel reaction of nitroalkanes with 4,5-diaminoacenaphthene in the presence of polyphosphoric acid. The reaction involves phosphorylation of the aci-nitro compound, followed by intramol...

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Главные авторы: Aksenov, A. V., Аксенов, А. В., Aksenov, N. A., Аксенов, Н. А., Ovcharov, D. S., Овчаров, Д. С., Shcherbakov, S. V., Щербаков, С. В., Smirnova, A. N., Смирнова, А. Н., Aksenova, I. V., Аксенова, И. В., Goncharov, V. I., Гончаров, В. И., Rubin, M. A., Рубин, М. А.
格式: Статья
語言:English
出版: Maik Nauka Publishing / Springer SBM 2018
主題:
Thin-film transistors
Channel organic semiconductors
Perylene bisimides
Acenes
Photovoltaics
Acetamination
Performance
Derivatives
Electronics
Perimidines
在線閱讀:https://www.scopus.com/record/display.uri?eid=2-s2.0-85028604314&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=0a0f0434fb9e513c7f0fb58254b47a91&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Electrophilically+activated+nitroalkanes+in+the+synthesis+of+6%2c7-dihydro-1H-cyclopenta%5bg%5dperimidines%29&relpos=1&citeCnt=1&searchTerm=
https://dspace.ncfu.ru/handle/20.500.12258/2962
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總結:A highly efficient synthetic route to 6,7-dihydro-1H-cyclopenta[gh]perimidines has been proposed on the basis of a novel reaction of nitroalkanes with 4,5-diaminoacenaphthene in the presence of polyphosphoric acid. The reaction involves phosphorylation of the aci-nitro compound, followed by intramolecular cyclization

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