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Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes

Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes

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A highly efficient synthetic method for expeditious and selective assembly of tetraazopyrenes (TAPy) is reported, based on the novel reaction of electrophilically activated nitroalkanes with aromatic amines. Remarkably, the nitroalkanes play a dual role in this process, also serving as mild and effi...

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Detalhes bibliográficos
Principais autores: Aksenov, A. V., Аксенов, А. В., Ovcharov, D. S., Овчаров, Д. С., Aksenov, N. A., Аксенов, Н. А., Aksenov, D. A., Аксенов, Д. А., Nadein, O. N., Надеин, О. Н., Rubin, M. A., Рубин, М. А.
Formato: Статья
Idioma:English
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Aerobic treatment
Aromatic amines
Dual role
Efficient synthesis
Nitroalkanes
Polyphosphoric acids
Selective assembly
Synthetic methods
Acesso em linha:https://www.scopus.com/record/display.uri?eid=2-s2.0-85021670891&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=506f935bdae2bbaa7c691f3dc6d28b92&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Dual+role+of+polyphosphoric+acid-activated+nitroalkanes+in+oxidative+peri+-annulations%3a+Efficient+synthesis+of+1%2c3%2c6%2c8-tetraazapyrenes%29&relpos=1&citeCnt=1&searchTerm=
https://dspace.ncfu.ru/handle/20.500.12258/2977
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https://www.scopus.com/record/display.uri?eid=2-s2.0-85021670891&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=506f935bdae2bbaa7c691f3dc6d28b92&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Dual+role+of+polyphosphoric+acid-activated+nitroalkanes+in+oxidative+peri+-annulations%3a+Efficient+synthesis+of+1%2c3%2c6%2c8-tetraazapyrenes%29&relpos=1&citeCnt=1&searchTerm=
https://dspace.ncfu.ru/handle/20.500.12258/2977

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