Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes
A highly efficient synthetic method for expeditious and selective assembly of tetraazopyrenes (TAPy) is reported, based on the novel reaction of electrophilically activated nitroalkanes with aromatic amines. Remarkably, the nitroalkanes play a dual role in this process, also serving as mild and effi...
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Royal Society of Chemistry
2018
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oai:10.200.131.19:20.500.12258-29772018-09-14T09:11:40Z Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes Aksenov, A. V. Аксенов, А. В. Ovcharov, D. S. Овчаров, Д. С. Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Nadein, O. N. Надеин, О. Н. Rubin, M. A. Рубин, М. А. Aerobic treatment Aromatic amines Dual role Efficient synthesis Nitroalkanes Polyphosphoric acids Selective assembly Synthetic methods A highly efficient synthetic method for expeditious and selective assembly of tetraazopyrenes (TAPy) is reported, based on the novel reaction of electrophilically activated nitroalkanes with aromatic amines. Remarkably, the nitroalkanes play a dual role in this process, also serving as mild and efficient oxidants promoting aromatization of the final product and allowing for the exclusion of a poorly controllable aerobic treatment 2018-09-14T09:11:08Z 2018-09-14T09:11:08Z 2017 Статья Aksenov, A.V., Ovcharov, D.S., Aksenov, N.A., Aksenov, D.A., Nadein, O.N., Rubin, M. Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes // RSC Advances. - 2017. - Volume 7. - Issue 48. - Pages 29927-29932 https://www.scopus.com/record/display.uri?eid=2-s2.0-85021670891&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=506f935bdae2bbaa7c691f3dc6d28b92&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Dual+role+of+polyphosphoric+acid-activated+nitroalkanes+in+oxidative+peri+-annulations%3a+Efficient+synthesis+of+1%2c3%2c6%2c8-tetraazapyrenes%29&relpos=1&citeCnt=1&searchTerm= http://hdl.handle.net/20.500.12258/2977 en RSC Advances application/pdf application/pdf Royal Society of Chemistry |
| institution |
СКФУ |
| collection |
Репозиторий |
| language |
English |
| topic |
Aerobic treatment Aromatic amines Dual role Efficient synthesis Nitroalkanes Polyphosphoric acids Selective assembly Synthetic methods |
| spellingShingle |
Aerobic treatment Aromatic amines Dual role Efficient synthesis Nitroalkanes Polyphosphoric acids Selective assembly Synthetic methods Aksenov, A. V. Аксенов, А. В. Ovcharov, D. S. Овчаров, Д. С. Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Nadein, O. N. Надеин, О. Н. Rubin, M. A. Рубин, М. А. Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes |
| description |
A highly efficient synthetic method for expeditious and selective assembly of tetraazopyrenes (TAPy) is reported, based on the novel reaction of electrophilically activated nitroalkanes with aromatic amines. Remarkably, the nitroalkanes play a dual role in this process, also serving as mild and efficient oxidants promoting aromatization of the final product and allowing for the exclusion of a poorly controllable aerobic treatment |
| format |
Статья |
| author |
Aksenov, A. V. Аксенов, А. В. Ovcharov, D. S. Овчаров, Д. С. Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Nadein, O. N. Надеин, О. Н. Rubin, M. A. Рубин, М. А. |
| author_facet |
Aksenov, A. V. Аксенов, А. В. Ovcharov, D. S. Овчаров, Д. С. Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Nadein, O. N. Надеин, О. Н. Rubin, M. A. Рубин, М. А. |
| author_sort |
Aksenov, A. V. |
| title |
Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes |
| title_short |
Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes |
| title_full |
Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes |
| title_fullStr |
Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes |
| title_full_unstemmed |
Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes |
| title_sort |
dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: efficient synthesis of 1,3,6,8-tetraazapyrenes |
| publisher |
Royal Society of Chemistry |
| publishDate |
2018 |
| url |
https://www.scopus.com/record/display.uri?eid=2-s2.0-85021670891&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=506f935bdae2bbaa7c691f3dc6d28b92&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Dual+role+of+polyphosphoric+acid-activated+nitroalkanes+in+oxidative+peri+-annulations%3a+Efficient+synthesis+of+1%2c3%2c6%2c8-tetraazapyrenes%29&relpos=1&citeCnt=1&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/2977 |
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