Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes

A highly efficient synthetic method for expeditious and selective assembly of tetraazopyrenes (TAPy) is reported, based on the novel reaction of electrophilically activated nitroalkanes with aromatic amines. Remarkably, the nitroalkanes play a dual role in this process, also serving as mild and effi...

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Հիմնական հեղինակներ:	Aksenov, A. V., Аксенов, А. В., Ovcharov, D. S., Овчаров, Д. С., Aksenov, N. A., Аксенов, Н. А., Aksenov, D. A., Аксенов, Д. А., Nadein, O. N., Надеин, О. Н., Rubin, M. A., Рубин, М. А.
Ձևաչափ:	Статья
Լեզու:	English
Հրապարակվել է:	Royal Society of Chemistry 2018
Խորագրեր:	Aerobic treatment Aromatic amines Dual role Efficient synthesis Nitroalkanes Polyphosphoric acids Selective assembly Synthetic methods
Առցանց հասանելիություն:	https://www.scopus.com/record/display.uri?eid=2-s2.0-85021670891&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=506f935bdae2bbaa7c691f3dc6d28b92&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Dual+role+of+polyphosphoric+acid-activated+nitroalkanes+in+oxidative+peri+-annulations%3a+Efficient+synthesis+of+1%2c3%2c6%2c8-tetraazapyrenes%29&relpos=1&citeCnt=1&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/2977
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spelling	oai:10.200.131.19:20.500.12258-29772018-09-14T09:11:40Z Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes Aksenov, A. V. Аксенов, А. В. Ovcharov, D. S. Овчаров, Д. С. Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Nadein, O. N. Надеин, О. Н. Rubin, M. A. Рубин, М. А. Aerobic treatment Aromatic amines Dual role Efficient synthesis Nitroalkanes Polyphosphoric acids Selective assembly Synthetic methods A highly efficient synthetic method for expeditious and selective assembly of tetraazopyrenes (TAPy) is reported, based on the novel reaction of electrophilically activated nitroalkanes with aromatic amines. Remarkably, the nitroalkanes play a dual role in this process, also serving as mild and efficient oxidants promoting aromatization of the final product and allowing for the exclusion of a poorly controllable aerobic treatment 2018-09-14T09:11:08Z 2018-09-14T09:11:08Z 2017 Статья Aksenov, A.V., Ovcharov, D.S., Aksenov, N.A., Aksenov, D.A., Nadein, O.N., Rubin, M. Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes // RSC Advances. - 2017. - Volume 7. - Issue 48. - Pages 29927-29932 https://www.scopus.com/record/display.uri?eid=2-s2.0-85021670891&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=506f935bdae2bbaa7c691f3dc6d28b92&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Dual+role+of+polyphosphoric+acid-activated+nitroalkanes+in+oxidative+peri+-annulations%3a+Efficient+synthesis+of+1%2c3%2c6%2c8-tetraazapyrenes%29&relpos=1&citeCnt=1&searchTerm= http://hdl.handle.net/20.500.12258/2977 en RSC Advances application/pdf application/pdf Royal Society of Chemistry
institution	СКФУ
collection	Репозиторий
language	English
topic	Aerobic treatment Aromatic amines Dual role Efficient synthesis Nitroalkanes Polyphosphoric acids Selective assembly Synthetic methods
spellingShingle	Aerobic treatment Aromatic amines Dual role Efficient synthesis Nitroalkanes Polyphosphoric acids Selective assembly Synthetic methods Aksenov, A. V. Аксенов, А. В. Ovcharov, D. S. Овчаров, Д. С. Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Nadein, O. N. Надеин, О. Н. Rubin, M. A. Рубин, М. А. Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes
description	A highly efficient synthetic method for expeditious and selective assembly of tetraazopyrenes (TAPy) is reported, based on the novel reaction of electrophilically activated nitroalkanes with aromatic amines. Remarkably, the nitroalkanes play a dual role in this process, also serving as mild and efficient oxidants promoting aromatization of the final product and allowing for the exclusion of a poorly controllable aerobic treatment
format	Статья
author	Aksenov, A. V. Аксенов, А. В. Ovcharov, D. S. Овчаров, Д. С. Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Nadein, O. N. Надеин, О. Н. Rubin, M. A. Рубин, М. А.
author_facet	Aksenov, A. V. Аксенов, А. В. Ovcharov, D. S. Овчаров, Д. С. Aksenov, N. A. Аксенов, Н. А. Aksenov, D. A. Аксенов, Д. А. Nadein, O. N. Надеин, О. Н. Rubin, M. A. Рубин, М. А.
author_sort	Aksenov, A. V.
title	Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes
title_short	Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes
title_full	Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes
title_fullStr	Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes
title_full_unstemmed	Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes
title_sort	dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: efficient synthesis of 1,3,6,8-tetraazapyrenes
publisher	Royal Society of Chemistry
publishDate	2018
url	https://www.scopus.com/record/display.uri?eid=2-s2.0-85021670891&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=north+caucasus+federal+university&sid=506f935bdae2bbaa7c691f3dc6d28b92&sot=afnl&sdt=sisr&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&ref=%28Dual+role+of+polyphosphoric+acid-activated+nitroalkanes+in+oxidative+peri+-annulations%3a+Efficient+synthesis+of+1%2c3%2c6%2c8-tetraazapyrenes%29&relpos=1&citeCnt=1&searchTerm= https://dspace.ncfu.ru/handle/20.500.12258/2977
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Dual role of polyphosphoric acid-activated nitroalkanes in oxidative peri -annulations: Efficient synthesis of 1,3,6,8-tetraazapyrenes

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