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Direct conversion of 3-(2-nitroethyl)-1H-indoles into 2-(1H-indol-2-yl)acetonitriles

Direct conversion of 3-(2-nitroethyl)-1H-indoles into 2-(1H-indol-2-yl)acetonitriles

The recently discovered [4+1]-spirocyclization of nitroalkenes to indoles provided a convenient new approach to 2-(1H-indol-2-yl)acetonitriles. However, this reaction was complicated by the formation of inert 3-(2-nitroethyl)-1H-indole byproducts. Herein, we offer a workaround this problem that allo...

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Autors principals: Aksenov, A. V., Аксенов, А. В., Aksenov, N. A., Аксенов, Н. А., Aleksandrova, E. V., Александрова, Е. В., Aksenov, D. A., Аксенов, Д. А., Grishin, I. Y., Гришин, И. Ю., Rubin, M. A., Рубин, М. А.
Format: Статья
Idioma:English
Publicat: MDPI 2021
Matèries:
Nitroalkanes
Cascade transformations
Heterocycles
1,2-alkyl shift
Rearrangements
Accés en línia:https://dspace.ncfu.ru/handle/20.500.12258/18235
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https://dspace.ncfu.ru/handle/20.500.12258/18235

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