Desymmetrization of cyclopropenes via the potassium-templated diastereoselective 7- exo- trig cycloaddition of tethered amino alcohols toward enantiopure cyclopropane-fused oxazepanones with antimycobacterial activity

Desymmetrization of cyclopropenes via the potassium-templated diastereoselective 7- exo- trig cycloaddition of tethered amino alcohols toward enantiopure cyclopropane-fused oxazepanones with antimycobacterial activity

A strain-release-driven, cation-templated intramolecular nucleophilic addition of tethered alkoxides to prochiral cyclopropenes is described. Employment of chiral β- and γ-amino alkoxides allowed for highly diastereoselective assembly of a small series of enantiopure cyclopropane-fused oxazepanones....

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Главные авторы:	Aksenov, N. A., Аксенов, Н. А., Rubin, M. A., Рубин, М. А.
格式:	Статья
语言:	English
出版:	American Chemical Society 2018
主题:	Desymmetrization of cyclopropenes
在线阅读:	https://www.scopus.com/record/display.uri?eid=2-s2.0-85047352177&origin=resultslist&sort=plf-f&src=s&nlo=1&nlr=20&nls=afprfnm-t&affilName=nort+caucas+fed+univ&sid=ebf9446ddab8c0101772b7f698064ac5&sot=afnl&sdt=afsp&sl=53&s=%28AF-ID%28%22North+Caucasus+Federal+University%22+60070541%29%29&relpos=3&citeCnt=0&searchTerm= https://dspace.ncfu.ru:443/handle/20.500.12258/385
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