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Preparation of stereodefined 2-(3-Oxoindolin-2-yl)-2-arylacetonitriles via one-pot reaction of indoles with nitroalkenes

Preparation of stereodefined 2-(3-Oxoindolin-2-yl)-2-arylacetonitriles via one-pot reaction of indoles with nitroalkenes

Recently discovered reactivity of nitrostyrenes in phosphorous acid to facilitate the diastereoselective [4 + 1]-cycloaddition of indoles in combination with unusual oxazoline ring cleavage and subsequent 1,2-alkyl shift afforded stereochemically defined 2-(3-oxoindolin-2-yl)-2-arylacetonitriles as...

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Hauptverfasser: Aksenov, A. V., Аксенов, А. В., Aksenov, D. A., Аксенов, Д. А., Aksenov, N. A., Аксенов, Н. А., Aleksandrova, E. V., Александрова, Е. В., Rubin, M. A., Рубин, М. А.
Format: Статья
Sprache:English
Veröffentlicht: American Chemical Society 2019
Schlagworte:
Chemistry
Diastereoselective
Nitroalkenes
One-pot reaction
Oxazoline ring
Phosphorous acid
Organic compounds
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https://www.scopus.com/record/display.uri?eid=2-s2.0-85072939054&origin=resultslist&sort=plf-f&src=s&st1=Preparation+of+Stereodefined+2-3-Oxoindolin-2-yl-2-Arylacetonitriles+via+One-Pot+Reaction+of+Indoles+with+Nitroalkenes&st2=&sid=02d9804609854217979d893e240f14a6&sot=b&sdt=b&sl=133&s=TITLE-ABS-KEY%28Preparation+of+Stereodefined+2-3-Oxoindolin-2-yl-2-Arylacetonitriles+via+One-Pot+Reaction+of+Indoles+with+Nitroalkenes%29&relpos=0&citeCnt=0&searchTerm=
https://dspace.ncfu.ru/handle/20.500.12258/8015

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